Today, 95% of all hydrogen is produced by reforming, a reaction of methane (CH4), the main component of natural gas, with steam.
Hydrogen is produced by a series of chemical reactions, at a high temperature (about 900°C), in the presence of catalysts.
First, methane is combined with water:
CH4 (methane) + H2O (water) → 3H2 (hydrogen) + CO (carbon monoxide)
The reaction then continues to convert the CO:
CO (carbon monoxide) + H2O (water) → H2 (hydrogen) + CO2 (carbon dioxide)
The global reaction of reforming by methane is therefore:
CH4 + 2H2O → 4H2 + CO2
This reaction produces a gaseous mixture that contains H2 and CO2, but also traces of H2O, CH4 and CO that have not reacted, as well as nitrogen (N2) that is often found mixed with natural gas. This mixture will be purified to obtain hydrogen.